Remote C(sp<sup>3</sup>)–H activation: palladium-catalyzed intermolecular arylation and alkynylation with organolithiums and terminal alkynes
Peng Chen, Zhiyong Wang, Jiaxin Wang, Xiao‐Shui Peng, Henry Ν. C. Wong
Abstract
A 1,4-palladium shift is regarded as one of the solutions towards the challenging remote C(sp 3 )–H activation.
Topics & Concepts
ChemistryPalladiumAlkynylationCatalysisTerminal (telecommunication)Intermolecular forceMedicinal chemistryCombinatorial chemistryOrganic chemistryMoleculeTelecommunicationsComputer scienceCatalytic C–H Functionalization MethodsCatalytic Cross-Coupling ReactionsRadical Photochemical Reactions