Melt-quenched porous organic cage glasses
Michael C. Brand, Francesca Greenwell, Rob Clowes, Benjamin D. Egleston, Aiting Kai, Andrew I. Cooper, Thomas D. Bennett, Rebecca L. Greenaway
Abstract
The melting and glass-forming behaviour of a range of organic cages was investigated, with quenching of melted liquid states providing molecular glasses, one of which exhibited improved gas uptake compared to the starting amorphous cage.
Topics & Concepts
CageAmorphous solidQuenching (fluorescence)Materials sciencePorosityGlass meltingCage effectMelting temperatureChemical engineeringComposite materialChemistryCrystallographyOrganic chemistryMoleculeFluorescenceOpticsPhysicsCombinatoricsEngineeringMathematicsCovalent Organic Framework ApplicationsLuminescence and Fluorescent MaterialsSupramolecular Chemistry and Complexes