Co-catalysis of rhodium/phosphoramidite catalyst and ZSM-35(10) for the tandem hydroformylation–acetalization of olefins
Zhe Shu, Xiuxiu Zhao, Zhaohui Zheng, Xueqing Zhang, Yushuang Zhang, Shuhui Sun, Jianbin Chen, Congxia Xie, Bing Yuan, Xiaofei Jia
Abstract
). Control experiments and DFT calculations indicated that the Rh/L11-catalyzed hydroformylation occurred in the solvent outside the molecular sieve, while the acetalization of intermediate aldehydes with alcohols takes place mainly in the interior of the molecular sieve.
Topics & Concepts
HydroformylationRhodiumCatalysisTandemPhosphoramiditeChemistryOrganic chemistryMaterials scienceOligonucleotideDNAComposite materialBiochemistryOrganometallic Complex Synthesis and CatalysisAsymmetric Hydrogenation and CatalysisCarbon dioxide utilization in catalysis