Between imide, imidyl and nitrene – an imido iron complex in two oxidation states
Sascha Reith, Serhiy Demeshko, Beatrice Battistella, Alexander Reckziegel, Christian Schneider, Andreas Stoy, Crispin Lichtenberg, Franc Meyer, Dominik Munz, C. Gunnar Werncke
Abstract
A pair of trigonal imido iron complexes ([Fe(NMes)L 2 ] 0,− ) in two oxidation states is reported. The anionic complex K{crypt.222}[Fe(NMes)L 2 ] is best described as an iron( ii ) imide.
Topics & Concepts
NitreneChemistryElectrophileReactivity (psychology)Medicinal chemistryPhotochemistryPhosphinePincer movementStereochemistryOrganic chemistryCatalysisPathologyMedicineAlternative medicineSynthesis and Catalytic ReactionsMetal-Catalyzed Oxygenation MechanismsCatalytic C–H Functionalization Methods