Pyridine-Catalyzed Atomic Layer Deposition of SiO<sub>2</sub> from Hexachlorodisilane and Water: An In Situ Mechanistic Study
Jieun Hyun, Hyeong-Jin Kim, Bonggeun Shong, Yo‐Sep Min
Abstract
Pyridine-catalyzed atomic layer deposition (ALD) of SiO 2 from hexachlorodisilane and water was studied by in situ analyses using Fourier-transform infrared spectrometry and a quartz crystal microbalance. Although it has been observed that ALD SiO 2 can grow even when only one half-reaction is catalyzed, typical self-limiting growth of SiO 2 by catalytic ALD has been achieved when both half-reactions are catalyzed by pyridine. The in situ analyses revealed that the unexpected growth of SiO 2, when only one half-reaction was catalyzed, was caused by the presence of residual pyridine that had not yet desorbed from the previous half-reaction. The retardation of catalyst desorption was more prominent on the OH-terminated SiO 2 surface than on the Cl-terminated surface, which is related to the significantly higher desorption energy of pyridine species on the hydroxyl surface calculated using density functional theory.