Hydration in aqueous NaCl
Christoph J. Sahle, Emmanuelle de Clermont Gallerande, Johannes Niskanen, A. Longo, Mirko Elbers, Martin A. Schroer, Christian Sternemann, Sandro Jahn
Abstract
-ions. By this combined experimental and theoretical approach, we find the strongest spectral changes to indeed result from the first hydration shells of both ions and relate the observed shift of spectral weight from the post- to the main-edge to the origin of the post-edge as a shape resonance.
Topics & Concepts
SolvationAqueous solutionIonChemical physicsChemistryExcited stateSolvation shellMolecular dynamicsSpectral lineAb initioComputational chemistryPhysical chemistryAtomic physicsPhysicsOrganic chemistryAstronomySpectroscopy and Quantum Chemical StudiesChemical and Physical Properties in Aqueous SolutionsMolecular spectroscopy and chirality