Mimic metalloenzymes with atomically dispersed Fe sites in covalent organic framework membranes for enhanced CO<sub>2</sub> photoreduction
Shuaiqi Gao, Xiao Zhao, Qian Zhang, Linlin Guo, Zhiyong Li, Huiyong Wang, Suojiang Zhang, Jianji Wang
Abstract
A mimic metalloenzyme fabricated by anchoring atomically dispersed Fe sites into interlayers of the triazine-based COF membrane ensures an enhanced performance for CO 2 photoreduction, like a high CO yield of 992 μmol g −1 h −1 and selectivity of 100%.
Topics & Concepts
Covalent bondMembraneMaterials scienceNanotechnologyCovalent organic frameworkChemistryChemical engineeringCombinatorial chemistryOrganic chemistryEngineeringBiochemistryCovalent Organic Framework ApplicationsAdvanced Photocatalysis TechniquesMetal-Organic Frameworks: Synthesis and Applications