LnDOTA puppeteering: removing the water molecule and imposing tetragonal symmetry
Anna Schannong Manvell, Rouven F. Pfleger, Niels Andreas Bonde, Matteo Briganti, Carlo Andrea Mattei, Theis Brock‐Nannestad, Høgni Weihe, Annie K. Powell, Jacques Ollivier, Jesper Bendix, Mauro Perfetti
Abstract
Ionic strength and solid state packing effects have been used to remove the coordinated water molecule from the LnDOTA complexes, allowing to understand the magnetic anisotropy and single molecule magnet properties of these complexes.
Topics & Concepts
Tetragonal crystal systemSymmetry (geometry)MoleculeChemical physicsChemistryPhysicsTheoretical physicsCrystallographyMaterials scienceQuantum mechanicsMathematicsCrystal structureGeometryMagnetism in coordination complexesLanthanide and Transition Metal ComplexesElectron Spin Resonance Studies