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3D Cage COFs: A Dynamic Three-Dimensional Covalent Organic Framework with High-Connectivity Organic Cage Nodes

Qiang Zhu, Xue Wang, Rob Clowes, Peng Cui, Linjiang Chen, Marc A. Little, Andrew I. Cooper

2020Journal of the American Chemical Society337 citationsDOIOpen Access PDF

Abstract

uptake and captures water at low humidity (<40%). This demonstrates the potential for expanding the structural complexity of 3D COFs by using organic cages as the building units.

Topics & Concepts

CageChemistryCovalent bondYield (engineering)Covalent organic frameworkTopology (electrical circuits)MoleculePrismFullereneNode (physics)NanotechnologyOrganic chemistryCombinatoricsComposite materialOpticsMaterials scienceStructural engineeringPhysicsEngineeringMathematicsCovalent Organic Framework ApplicationsMetal-Organic Frameworks: Synthesis and ApplicationsLuminescence and Fluorescent Materials