Litcius/Paper detail

Selective, Anisotropic, or Consistent Polarized‐Photon Out‐Coupling of 2D Organic Microcrystals

Zhong‐Qiu Li, Dian‐Xue Ma, Fa‐Feng Xu, Ti‐Xiong Dan, Zhong‐Liang Gong, Jiang‐Yang Shao, Yong Sheng Zhao, Jiannian Yao, Yu‐Wu Zhong

2022Angewandte Chemie International Edition31 citationsDOI

Abstract

Nano- and micromaterials with anisotropic photoluminescence and photon transport have widespread application prospects in quantum optics, optoelectronics, and displays. But the nature of the polarization information of the out-coupled light, with respect to that of the source luminescence, has never been explored in active optical-waveguiding organic crystals. Herein, three different modes (selective, anisotropic, and consistent) of polarized-photon out-coupling are proposed and successfully implemented in a set of 2D organic microcrystals with highly linearly-polarized luminescence. It is found that the polarization direction and degree of the luminescence out-coupled through different waveguiding channels can either be essentially retained or distinctly changed with respect to those of the original luminescence, depending on the molecular arrangement and the orientation of transition dipole moments of the crystal. This work demonstrates the promising potential of 2D emissive microcrystals in multi-channel polarized photon transport.

Topics & Concepts

LuminescencePhotoluminescenceAnisotropyPolarization (electrochemistry)Materials sciencePhotonDipoleMolecular physicsCoupling (piping)OptoelectronicsOptical anisotropyOpticsPhysicsChemistryQuantum mechanicsMetallurgyPhysical chemistryLuminescence and Fluorescent MaterialsStrong Light-Matter InteractionsPerovskite Materials and Applications