High-performance freestanding supercapacitor electrode based on polypyrrole coated nickel cobalt sulfide nanostructures
Mohammad Barazandeh, Sayed Habib Kazemi
Abstract
Abstract In the present work, we report the successful fabrication of dandelion-like Nickel–Cobalt Sulfide@Polypyrrole microspheres through the hydrothermal method and its possible application as a binder-free electrode in supercapacitors. This electrode exhibited low charge transfer resistance with a remarkable specific capacitance of 2554.9 F g −1 at 2.54 A g −1 , in addition to considerable cycle life stability. Also, an asymmetric device was prepared using NiCo 2 S 4 @PPy/NF as positive and rGO/NF as negative electrodes. This asymmetric supercapacitor exhibited a specific capacitance of 98.9 F g −1 at 1.84 A g −1 and delivered an energy density of 35.17 Wh kg −1 at a power density of 1472 W kg −1 . Such a remarkable performance can be originated from the synergy effect of NiCo 2 S 4 and PPy and the direct deposition of the composite on the current collector. Our findings suggest the dandelion-like NiCo 2 S 4 @PPy as a promising material for making high-performance supercapacitors.