Radical generation enabled by photoinduced N–O bond fragmentation
Edward J. McClain, Alan Wortman, Corey R. J. Stephenson
Abstract
-oxide provides access to primary, secondary, and tertiary radical intermediates, and its application toward the development of a photochemical Minisci alkylation is reported.
Topics & Concepts
ChemistryPhotochemistryFragmentation (computing)QuinolineAlkylationPrimary (astronomy)Combinatorial chemistryOrganic chemistryCatalysisComputer scienceAstronomyPhysicsOperating systemRadical Photochemical ReactionsCatalytic C–H Functionalization MethodsOxidative Organic Chemistry Reactions