Tribology of MXene Materials: Advances, Challenges, and Future Directions
Jonathan Luke Stoll, May Paul, Lucas Pritchett, A.M. Vaysburd R.M. Snover, Levi Woods, Subin Antony Jose, Pradeep L. Menezes
Abstract
MXenes, an emerging class of two-dimensional (2D) transition metal carbides, nitrides, and carbonitrides, have demonstrated exceptional potential in tribology: the study of friction, wear, and lubrication. Their remarkable mechanical strength, thermal stability, and tunable surface chemistry make them ideal candidates for solid lubricants, lubricant additives, and protective coatings in mechanical systems. This review comprehensively examines the tribological performance of MXenes under diverse environmental conditions, including high temperatures, vacuum, humid atmospheres, and liquid lubricants. A particular emphasis is placed on the influence of surface terminations (-OH, -O, -F) on friction reduction and wear resistance. Additionally, we discuss strategies for enhancing MXene performance through hybridization with polymers, nanoparticles, and ionic liquids, enabling superior durability in applications ranging from micro/nano-electromechanical systems (MEMS/NEMS) to aerospace and biomedical devices. We also highlight recent advances in experimental characterization techniques and computational modeling, which provide deeper insights into MXene tribomechanics. Despite their promise, key challenges such as oxidation susceptibility, high synthesis costs, and performance variability hinder large-scale commercialization. Emerging solutions, including eco-friendly synthesis methods and optimized composite designs, are explored as pathways to overcome these limitations. Overall, MXenes represent a transformative avenue for developing next-generation tribological materials that combine high efficiency, sustainability, and multifunctionality. Continued research and innovation in this field could unlock groundbreaking advancements across industrial and engineering applications.