Subcomponent self-assembly of circular helical Dy6(L)6 and bipyramid Dy12(L)8 architectures directed <i>via</i> second-order template effects
Xiaolei Li, Lang Zhao, Jianfeng Wu, Wei Shi, Niklas Struch, Arne Lützen, Annie K. Powell, Peng Cheng, Jinkui Tang
Abstract
Subcomponent self-assembly gave access to Dy12(L)8 and Dy6(L)6 architectures via second-order template effects. The Dy6(L)6 assembly behaves as a single-molecule magnet exhibiting a high anisotropy barrier and butterfly-shaped magnetic hysteresis.
Topics & Concepts
Order (exchange)BipyramidMathematicsStereochemistryCombinatoricsChemistryCrystallographyFinanceEconomicsCrystal structureLanthanide and Transition Metal ComplexesMagnetism in coordination complexesSupramolecular Chemistry and Complexes