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Carrier dynamic monitoring of a π-conjugated polymer: a surface-enhanced Raman scattering method

Xinyuan Zhang, Shuo Yang, Lili Yang, Daxin Zhang, Yansen Sun, Zhenyu Pang, Jinghai Yang, Lei Chen

2020Chemical Communications27 citationsDOI

Abstract

Here, the carrier dynamics of a π-conjugated polymer is monitored by voltage-dependent surface-enhanced Raman scattering (SERS). The conductive polymer poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) is employed as a metal-free SERS substrate. Under different voltage conditions, the SERS performance of the semiconductors' rectification characteristic is discussed. Our results open an unprecedented regime for conducting polymer-based SERS.

Topics & Concepts

PEDOT:PSSConjugated systemRaman scatteringMaterials scienceConductive polymerPolymerSubstrate (aquarium)RectificationNanotechnologyOptoelectronicsRaman spectroscopyVoltageOpticsComposite materialPhysicsOceanographyQuantum mechanicsGeologyConducting polymers and applicationsGold and Silver Nanoparticles Synthesis and ApplicationsAdvanced Nanomaterials in Catalysis