Annulated carbocyclic gallylene and bis-gallylene with two-coordinated Ga(<scp>i</scp>) atoms
Arne Merschel, Shkelqim Heda, Yury V. Vishnevskiy, Beate Neumann, Hans‐Georg Stammler, Rajendra S. Ghadwal
Abstract
The first carbocyclic gallylene [(ADC) 2 Ga(GaI 2 )] and bis-gallylene [(ADC)Ga] 2 (ADC = PhC{N(Dipp)C} 2 ; Dipp = 2,6-iPr 2 C 6 H 3 ) featuring a central C 4 Ga 2 ring annulated between two 1,3-imidazole rings are prepared by KC 8 reductions of [(ADC)GaI 2 ] 2 .
Topics & Concepts
ChemistryStereochemistryCrystallographyMedicinal chemistrySynthesis and characterization of novel inorganic/organometallic compoundsCoordination Chemistry and OrganometallicsOrganometallic Complex Synthesis and Catalysis