Lead-Free BF–BT Ceramics With Ultrahigh Curie Temperature for Piezoelectric Accelerometer
Huabin Yang, Yuanyuan Sun, Huayun Gao, Xinyi Zhou, Hua Tan, C. Shu, David Salamon, Shibo Guan, Shenggui Chen, Haibo Zhang
Abstract
Piezoelectric ceramics have been widely used in high precision sensors such as vibration detection, but piezoelectric accelerometers in high-temperature applications are very rare. We prepared ( <inline-formula xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink"> <tex-math notation="LaTeX">$1- {x}$ </tex-math></inline-formula> ) BiFeO3- <inline-formula xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink"> <tex-math notation="LaTeX">${x}$ </tex-math></inline-formula> BaTiO3-0.0035MnO2-0.001Li2CO3(BF- <inline-formula xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink"> <tex-math notation="LaTeX">${x}$ </tex-math></inline-formula> BT) ceramics by a solid state approach, and investigated the effect of BT content( <inline-formula xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink"> <tex-math notation="LaTeX">${x}$ </tex-math></inline-formula> ) on the phase structure, microstructure, dielectric properties, ferroelectric properties, piezoelectric properties, temperature stability, and especially the sensitivity of the piezoelectric accelerometer. The crystal structure of the sample is pure perovskite structure with the MPB (R and P phases) locating in a composition range of <inline-formula xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink"> <tex-math notation="LaTeX">$0.28\le {x} \le0.32$ </tex-math></inline-formula> for BF-xBT ceramics, and the single R phase exist at <inline-formula xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink"> <tex-math notation="LaTeX">$0.20\le {x} < 0.28$ </tex-math></inline-formula> . When <inline-formula xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink"> <tex-math notation="LaTeX">${x} $ </tex-math></inline-formula> = 0.30, the ceramic presents both high Curie temperature and <inline-formula xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink"> <tex-math notation="LaTeX">${d}_{33}$ </tex-math></inline-formula> . Notably, the sensitivity of BF-0.30BT piezoelectric accelerometer reaches the highest value of about 40 pC/g and shows an excellent stability until 400 °C, indicating that this material is a promising candidate for high-temperature piezoelectric accelerometer applications.