Air-stable chiral mono- and dinuclear dysprosium single-molecule magnets: steric hindrance of hexaazamacrocycles
Chen Zhao, Zhenhua Zhu, Xiaolei Li, Jinkui Tang
Abstract
Two pairs of air-stable chiral Dy-SMMs were constructed using different sterically hindered hexaazamacrocycles as equatorial ligands, leading to a nuclearity increase from 1 to 2.
Topics & Concepts
DysprosiumSteric effectsMoleculeMagnetCrystallographyMaterials scienceChemistryInorganic chemistryStereochemistryOrganic chemistryPhysicsQuantum mechanicsMagnetism in coordination complexesPorphyrin and Phthalocyanine ChemistryLanthanide and Transition Metal Complexes