Visible-light-promoted divergent functionalizations of methylenecyclopropanes
Baoxiang Zhu, Zhao Wang, Zhao Wang, Hui Xi, Zengqiang Feng, Binglei Wang, Wenyang Jiao, Zhongxian Li, Zechao Wang, Zechao Wang, Junliang Wu
Abstract
Visible-light-induced monofunctionalization and difunctionalization of MCPs via ring-opening and cyclization processes have been developed for the syntheses of difluoromethyl compounds, alkyl compounds, halides, and sulfonyl compounds.
Topics & Concepts
ChemistryHalideAlkylRing (chemistry)SulfonylVisible spectrumCombinatorial chemistryPhotochemistryOrganic chemistryOptoelectronicsPhysicsCyclopropane Reaction MechanismsSulfur-Based Synthesis TechniquesRadical Photochemical Reactions