Dearomatization of benzopyrylium triflates with sulfoxonium ylides
Alexandria N. Leveille, Marissa M. Allegrezza, Kalen Laybourn, Anita E. Mattson
Abstract
]oxepines. Control over the absolute stereochemistry of the process is possible when the reaction is executed under the influence of a suitable anion-binding catalyst.
Topics & Concepts
CyclopropanationRing (chemistry)ChemistrySequence (biology)Organic chemistryCatalysisBiochemistryCyclopropane Reaction MechanismsAsymmetric Synthesis and CatalysisSynthetic Organic Chemistry Methods