Rare-earth acetates as alternative precursors for rare-earth cluster-based metal–organic frameworks
Micaela Richezzi, P. Rafael Donnarumma, Christopher Copeman, Ashlee J. Howarth
Abstract
RE-UiO-66 analogues are synthesized using RE acetates as precursors for the first time. These MOFs are fully characterized and the influence of the precursor on the materials obtained is studied. Additionally, the influence of water on the yield of the syntheses and the quality of the materials is explored.
Topics & Concepts
Rare earthEarth (classical element)Metal-organic frameworkChemistryMetalCluster (spacecraft)AstrobiologyCombinatorial chemistryNanotechnologyMaterials scienceOrganic chemistryMineralogyAdsorptionComputer sciencePhysicsMathematical physicsProgramming languageMetal-Organic Frameworks: Synthesis and ApplicationsNanocluster Synthesis and ApplicationsLanthanide and Transition Metal Complexes