Recent Progress on 1,2-Metallate Shift Reactions Based on Tetracoordinate Boron Intermediates
Feng Zhang, Zhou Lü, Kai Yang, Qiuling Song
Abstract
Organoboron compounds are important and versatile synthetic building blocks in synthetic chemistry. Owing to the unique characteristics, they manifest great value in organic synthesis. In view of the versatile transformations, migration reactions of organoboron compounds have attracted great attention from chemists in recent years due to their high efficiency and mild reaction conditions, which are widely utilized for rapid constructions of carbon-carbon and carbon-heteroatom bonds. Recent progress on 1,2-migration reactions based on tetracoordinate boron intermediates is summarized according to various reaction conditions and bond formations.
Topics & Concepts
TetracoordinateChemistryBoronOrganic chemistryPlanarComputer scienceComputer graphics (images)Organoboron and organosilicon chemistryCoordination Chemistry and OrganometallicsAsymmetric Hydrogenation and Catalysis