Cyanide-Bridged Fe-Co Polynuclear Clusters Based on Four-Coordinate Cobalt(II)
Yue Cheng, Ziyi Chen, Kai‐Ping Xie, Yi‐Fei Deng, Yanxin Jiang, Qi Liu, Yuan‐Zhu Zhang
Abstract
behaved as a single-molecule magnet with an effective energy barrier for spin reverse of 30.7 K at zero dc field. Our result demonstrated a possible self-assembly route toward high-nuclearity cyanide-bridged clusters by introducing four-coordinate cobalt(II) ions.
Topics & Concepts
ChemistryCobaltCrystallographyOctahedronTrigonal bipyramidal molecular geometryCluster (spacecraft)BoronCyanideTetrahedral molecular geometryIonCoordination sphereStereochemistryInorganic chemistryCrystal structureOrganic chemistryComputer scienceProgramming languageMagnetism in coordination complexesInorganic Chemistry and MaterialsOrganic and Molecular Conductors Research