Too much water? Not enough? <i>In situ</i> monitoring of the mechanochemical reaction of copper salts with dicyandiamide
Lucia Casali, Torvid Feiler, Maria Heilmann, Dario Braga, Franziska Emmerling, Fabrizia Grepioni
Abstract
In situ monitoring, via X-ray and Raman spectroscopy, of mechanochemical reactions between dicyandiamide and copper( ii ) salts shows that the amount of added water and the milling frequency strongly impact on the products of the solid state synthesis.
Topics & Concepts
CopperIn situRaman spectroscopyChemistrySolid-stateFourier transform infrared spectroscopyInorganic chemistryChemical engineeringOrganic chemistryPhysical chemistryOpticsPhysicsEngineeringCrystallography and molecular interactionsPhenothiazines and Benzothiazines Synthesis and ActivitiesMetal-Organic Frameworks: Synthesis and Applications