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Pb<sub>2</sub>(SeO<sub>3</sub>)(SiF<sub>6</sub>): the first selenite fluorosilicate with a wide bandgap and large birefringence achieved through perfluorinated group modification

Pengfei Li, Chun‐Li Hu, Jiang‐Gao Mao, Fang Kong

2024Chemical Science39 citationsDOIOpen Access PDF

Abstract

polyhedrons. Our research not only pioneers a new system for selenite materials, enriching the diversity of selenite structures, but also provides a design methodology for obtaining wide bandgap birefringent selenite.

Topics & Concepts

SeleniumGroup (periodic table)Band gapBirefringenceChemistryInorganic chemistryMaterials scienceAnalytical Chemistry (journal)OptoelectronicsOpticsOrganic chemistryPhysicsInorganic Fluorides and Related CompoundsCrystal Structures and PropertiesLuminescence Properties of Advanced Materials