Mn-catalyzed electrooxidative radical phosphorylation of 2-isocyanobiaryls
Kaifang Fu, Juncai Jiang, Qiang Zhao, Nan Wang, Weiguang Kong, Yongqi Yu, Huanping Xie, Ting Li
Abstract
As an efficient and green synthesis method, the electrocatalysis hydrogen evolution coupling reaction has been widely used by chemists to realize the combining of two nucleophiles. In this work, an alternative method to synthesize 6-phosphorylated phenanthridines has been developed by synergistically utilizing electrocatalysis and Mn catalysis, with moderate to relatively good yields achieved. Mild and oxidant-free conditions make this synthetic method applicable in various settings.
Topics & Concepts
ElectrocatalystCatalysisNucleophileChemistryCombinatorial chemistryWork (physics)Organic chemistryElectrochemistryPhysical chemistryEngineeringElectrodeMechanical engineeringRadical Photochemical ReactionsSulfur-Based Synthesis TechniquesPolyoxometalates: Synthesis and Applications