Electrosynthesis of H2O2 through a two-electron oxygen reduction reaction by carbon based catalysts: From mechanism, catalyst design to electrode fabrication
Jingkun An, Yujie Feng, Qian Zhao, Xin Wang, Jia Liu, Nan Li
Abstract
Hydrogen peroxide (H2O2) is an efficient oxidant with multiple uses ranging from chemical synthesis to wastewater treatment. The in-situ H2O2 production via a two-electron oxygen reduction reaction (ORR) will bring H2O2 beyond its current applications. The development of carbon materials offers the hope for obtaining inexpensive and high-performance alternatives to substitute noble-metal catalysts in order to provide a full and comprehensive picture of the current state of the art treatments and inspire new research in this area. Herein, the most up-to-date findings in theoretical predictions, synthetic methodologies, and experimental investigations of carbon-based catalysts are systematically summarized. Various electrode fabrication and modification methods were also introduced and compared, along with our original research on the air-breathing cathode and three-phase interface theory inside a porous electrode. In addition, our current understanding of the challenges, future directions, and suggestions on the carbon-based catalyst designs and electrode fabrication are highlighted.