Olefin metathesis over supported MoO<sub><i>x</i></sub> catalysts: influence of the oxide support
Bin Zhang, Michael E. Ford, Eli M. Ream, Israel E. Wachs
Abstract
Supported MoO x catalysts on oxide supports (Al 2 O 3 , TiO 2 , ZrO 2 , SiO 2 ) were synthesized for propylene metathesis, characterized with in situ spectroscopies (DRIFTS, Raman, UV-vis) and chemically probed with propylene-TPSR, ethylene/2-butene titration.
Topics & Concepts
CatalysisPropeneMetathesisRaman spectroscopyOlefin metathesisOlefin fiberOxideEthyleneTitrationPropylene oxideEthylene oxideInorganic chemistrySalt metathesis reactionMaterials scienceChemistryOrganic chemistryPolymerizationCopolymerOpticsPolymerPhysicsCatalysis and Hydrodesulfurization StudiesSynthetic Organic Chemistry MethodsCatalysis and Oxidation Reactions