Efficient access to β-amino acid ester/β-amino ketone derivatives <i>via</i> photocatalytic radical alkoxycabonylimidation/carbonylimidation of alkenes
Peng‐Ju Xia, Fu Liu, Ying‐Ming Pan, Meng-Ping Yang, Yun-Yi Yang
Abstract
A photocatalytic protocol for the synthesis of β-amino acid ester and β-amino ketone derivatives is developed using simple and easy-to-synthesize oxime oxalate and oxime phenylglyoxylate as difunctionalization reagents.
Topics & Concepts
ChemistryKetonePhotocatalysisAmino acidOrganic chemistryBiochemistryCatalysisRadical Photochemical ReactionsSulfur-Based Synthesis TechniquesCatalytic C–H Functionalization Methods