(3 + 2) cycloaddition of 2-alkoxynaphthalenes with azaoxyallyl cations: access to benzo[<i>e</i>]indolones
Subrata Biswas, Surajit Duari, Srabani Maity, Arnab Roy, Asma M. Elsharif, Srijit Biswas
Abstract
A route to functionalized benzo[ e ]indolones has been reported via (3 + 2) cycloaddition of in situ generated azaoxyallyl cations with alkoxynaphthalene followed by aryl C–O bond cleavage. The intermediate adduct has been isolated and characterized.
Topics & Concepts
ChemistryCycloadditionStereochemistryBond cleavageMoleculeArylMedicinal chemistryDerivative (finance)Cleavage (geology)Combinatorial chemistryOrganic chemistryCatalysisFracture (geology)Financial economicsEngineeringEconomicsGeotechnical engineeringAlkylSynthesis and Biological EvaluationSynthesis and Reactions of Organic CompoundsStructural and Chemical Analysis of Organic and Inorganic Compounds