Ni/NHC catalysis in C–H functionalization using air-tolerant nickelocene and sodium formate for <i>in situ</i> catalyst generation
Oleg V. Khazipov, Konstantin E. Shepelenko, Dmitry V. Pasyukov, Vasilii V. Chesnokov, Safarmurod B. Soliev, Victor M. Chernyshev, Valentine P. Ananikov
Abstract
A facile method for Ni/NHC catalyzed C–H alkylation and alkenylation of heteroarenes with alkenes and internal alkynes using air-tolerant nickelocene, sodium formate and NHC·HCl salts for <italic>in situ</italic> catalyst generation has been developed.
Topics & Concepts
ChemistryCatalysisNickeloceneSodium formateIn situAlkylationSodiumFormateOrganic chemistryMedicinal chemistryFerroceneElectrodeElectrochemistryPhysical chemistryCatalytic C–H Functionalization MethodsCatalytic Cross-Coupling ReactionsN-Heterocyclic Carbenes in Organic and Inorganic Chemistry