<i>In situ</i> generated 2,5-pyrazinedicarboxylate and oxalate ligands leading to a Eu-MOF for selective capture of C<sub>2</sub>H<sub>2</sub> from C<sub>2</sub>H<sub>2</sub>/CO<sub>2</sub>
Fenglan Liang, De‐Yun Ma, Liang Qin, Qiuqun Yu, Jing Wen Chen, Rongxi Liang, Changheng Zhong, Huanzong Liao, Zhiyi Peng
Abstract
A new Eu-MOF is prepared, involving in situ generation of oxalate and 2,5-pyrazinedicarboxylate ligands, and activated at different temperatures to obtain two MOFs (1a and 1b), in which 1b is able to selectively capture C 2 H 2 from C 2 H 2 /CO 2 .
Topics & Concepts
In situOxalateChemistryCombinatorial chemistryInorganic chemistryOrganic chemistryMetal-Organic Frameworks: Synthesis and ApplicationsCarbon dioxide utilization in catalysisCatalytic Processes in Materials Science