Molybdenum-iron–cobalt oxyhydroxide with rich oxygen vacancies for the oxygen evolution reaction

Abstract

, and a long stable operation time (>50 h) in alkaline media, comparable to the current best OER catalyst. Moreover, it is demonstrated that the doping of iron favors the generation of oxygen vacancies. It is also found in this work that using a certain amount (5 mg) of iron dopant can alter the electronic structure of the catalyst by tuning the electronic density around the metal ions, thus optimizing the binding energy of intermediates. The present work unveils the doping effect of iron and molybdenum on the construction of trimetallic oxyhydroxide catalysts, and sheds light on the relationship between the catalyst components and catalytic performance of the OER.

Topics & Concepts