The role of hypervalent iodine(<scp>iii</scp>) reagents in promoting alkoxylation of unactivated C(sp<sup>3</sup>)–H bonds catalyzed by palladium(<scp>ii</scp>) complexes
Payam Abdolalian, Samaneh K. Tizhoush, Kaveh Farshadfar, Alireza Ariafard
Abstract
a Pd(ii)-Pd(iv)-Pd(ii) catalytic cycle, the other alternative in which the oxidation state of the Pd(ii) centre remains unchanged during the catalysis could be operative, depending on the nature of the organic substrate.
Topics & Concepts
Hypervalent moleculeIsomerizationIodineCatalysisPalladiumChemistryReagentMedicinal chemistryStereochemistryOrganic chemistryCatalytic C–H Functionalization MethodsOxidative Organic Chemistry ReactionsSynthesis and Catalytic Reactions