Solvent-dependent <i>fac</i>/<i>mer</i>-isomerization and self-assembly of triply helical complexes bearing a pivot part
Takuma Morozumi, Ryota Matsuoka, Takashi Nakamura, Tatsuya Nabeshima
Abstract
isomer even though a mixture of the two isomers existed in solution before the condensation reaction. Namely, the self-assembly formation effectively adjusted the geometries of the building unit that results in the suitable supramolecular structure.
Topics & Concepts
IsomerizationImineChemistryBearing (navigation)SolventHelix (gastropod)Self-assemblyStereochemistryPolymer chemistryCrystallographyOrganic chemistryCatalysisPhysicsSnailEcologyAstronomyBiologySupramolecular Chemistry and ComplexesMolecular Sensors and Ion DetectionSupramolecular Self-Assembly in Materials