CoP and Ni<sub>2</sub>P implanted in a hollow porous N-doped carbon polyhedron for pH universal hydrogen evolution reaction and alkaline overall water splitting
Run Zhang, Ruolin Zhu, Ye Li, Hui Zhi, Yuyan Song, Yongliang Cheng, Jinjun Lü
Abstract
Developing low-cost and highly active bifunctional electrocatalysts for water splitting is very important but still remains a challenge. Herein, a novel bifunctional electrocatalyst composed of CoP and Ni2P nanoparticles implanted in a hollow porous N-doped carbon polyhedron (CoP/Ni2P@HPNCP) is synthesized by carbonization of Co/Ni-layered double hydroxide@zeolitic imidazolate framework-67 (Co/Ni-LDH@ZIF-67) followed by an oxidation and phosphorization strategy. The introduction of LDH can not only promote the formation of a hollow porous structure to supply more active sites, but also generate the CoP/Ni2P nanoheterostructure to afford extra active sites and modulate the electronic structure of the catalyst. As a result, CoP/Ni2P@HPNCP exhibits excellent pH universal hydrogen evolution reaction activity and alkaline oxygen evolution reaction activity. Furthermore, the electrolytic cell assembled from bifunctional CoP/Ni2P@HPNCP requires a cell voltage of 1.59 V in 1.0 M KOH at 10 mA cm-2, revealing its potential as a high performance bifunctional electrocatalyst.