Impact of the position of nitrogen atom on the liquid crystal, optical and multi-stimuli response behaviors of rod-like mesogens containing multiple functional building blocks
Manshi Zeng, Yurun Liang, Na Liu, Xiaotong Liu, Yulong Xiao, Yulong Xiao
Abstract
Two novel rod-like mesogens containing one cyanostyrene, one pyridine and one pyrene as π-conjugate rigid core were designed and synthesized by Suzuki coupling and Knoevenagel reactions . The effect of the position of nitrogen-atom on the thermodynamic behavior, liquid crystalline self-assembly, optical behavior, mechanochromism behavior and acidochromism behavior was investigated. The rod-like mesogen in which the nitrogen atom is adjacent to the pyrene displays a phase transition from smectic A to smectic C by increasing temperature, whereas the other rod-like mesogen can only self-assemble into smectic C phase. This difference in mesophase transition behavior might be attributed to the position of nitrogen-atom which induces the change in molecular configuration. Both mesogens exhibit positive solvatochromism and high fluorescence in both solution state and aggregated state which might be attributed to the intramolecular charge transfer and twisted molecular configurations, respectively. Reversible mechanochromism behavior due to changes in molecular stacking and acidochromism behavior due to protonation and deprotonation were also achieved. These multi-stimuli responsive behaviors of the designed rod-like mesogens demonstrate potential applications in the field of multifunctional materials.