Synthesis and luminescent properties of hetero-bimetallic and hetero-trimetallic Ru(<scp>ii</scp>)/Au(<scp>i</scp>) or Ir(<scp>iii</scp>)/Au(<scp>i</scp>) complexes
Richard C. Knighton, Simon J. A. Pope
Abstract
= 616-629 nm) that were consistent with the parent Ru(II) or Ir(III) lumophores in each case. The modulation of the emission from the Ru(II)-Au(I) complexes was much more strongly evident than for the Ir(III)-Au(I) analogues, which is ascribed to the inherent differences in the specific triplet excited state character of the emitting states within each heterometallic species.
Topics & Concepts
Bimetallic stripLuminescenceChemistryRutheniumCrystallographyStereochemistryMaterials scienceMetalCatalysisOrganic chemistryOptoelectronicsMagnetism in coordination complexesOrganometallic Complex Synthesis and CatalysisMetal complexes synthesis and properties