Litcius/Paper detail

Carbene-like reactivity of methoxy groups in a single crystal SAPO-34 MTO catalyst

Ivalina B. Minova, Michæl Bühl, Santhosh Kumar Matam, C. Richard A. Catlow, Mark D. Frogley, Gianfelice Cinque, Paul A. Wright, Russell F. Howe

2022Catalysis Science & Technology20 citationsDOIOpen Access PDF

Abstract

In situ synchrotron infrared microspectroscopy on single crystals of SAPO-34 reveals that a carbene insertion mechanism is responsible for the first carbon–carbon bond formation from surface methoxy groups.

Topics & Concepts

CatalysisReactivity (psychology)CarbeneChemistryCrystal (programming language)Combinatorial chemistryOrganic chemistryComputer scienceProgramming languageMedicinePathologyAlternative medicineZeolite Catalysis and SynthesisChemical Synthesis and CharacterizationPolyoxometalates: Synthesis and Applications
Carbene-like reactivity of methoxy groups in a single crystal SAPO-34 MTO catalyst | Litcius