New 8-Hydroxyquinoline-Bearing Quinoxaline Derivatives as Effective Corrosion Inhibitors for Mild Steel in HCl: Electrochemical and Computational Investigations
Abdelkarim Chaouiki, Maryam Chafiq, Mohamed Rbaa, Hassane Lgaz, R. Salghi, B. Lakhrissi, Ismat H. Ali, Sheerin Masroor, Youngjae Cho
Abstract
There has been substantial research undertaken on the role of green synthesized corrosion inhibitors as a substantial approach to inhibit the corrosion of metals and their alloys in acidic environments. Herein, electrochemical studies, surface characterization, and theoretical modeling were adopted to investigate the corrosion inhibition proprieties of novel synthesized quinoxaline derivatives bearing 8-Hydroxyquinoline, namely 1-((8-hydroxyquinolin-5-yl) methyl)-3,6-dimethylquinoxalin-2(1H)-one (Q1) and 1-((8-hydroxyquinolin-5-yl)methyl) quinoxalin-2(1H)-one (Q2) on mild steel corrosion in 1 mol/L HCl solution. The principal finding of this research was that both inhibitors acted as good corrosion inhibitors with Q1 having the highest performance (96% at 5 × 10−3 mol/L). Electrochemical results obtained via potentiodynamic polarization (PDP) and electrochemical impedance spectroscopy (EIS) techniques demonstrated that quinoxaline compounds belonged to mixed-type inhibitors; their presence significantly increased the polarization resistance, preventing simultaneously anodic and cathodic reactions. Further, experimental results provided preliminary insights about the interactions mode between studied molecules and the mild steel surface, which followed the Langmuir adsorption model, and physical and chemical interactions assisted their inhibition mechanism. Besides, SEM analyses confirmed the existence of protective film on the metal surface after the addition of 5 × 10−3 mol/L of quinoxalines. In addition, the temperature and immersion time effects on inhibition performances of quinoxalines were investigated to evaluate their performances in different operating conditions. Besides, Density Functional Theory (DFT) and molecular dynamics (MD) simulations were carried out to explore the most reactive sites of quinoxaline inhibitors and their interaction mechanism. Theoretical results revealed that the inhibitor molecule with additional electron-donating functional group strongly interacted with the steel surface.