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Pyrolytic Carbon: An Inexpensive, Robust, and Versatile Electrode for Synthetic Organic Electrochemistry

Tamara El‐Hayek Ewing, Nils Kurig, Yoshio Robert Yamaki, Jiawei Sun, Timothy Knowles, Asha Gollapudi, Yu Kawamata, Phil S. Baran

2024Angewandte Chemie International Edition14 citationsDOIOpen Access PDF

Abstract

Synthetic organic electrochemistry is recognized as one of the most sustainable forms of redox chemistry that can enable a wide variety of useful transformations. In this study, readily prepared pyrolytic carbon electrodes are explored in several powerful rAP transformations as well as C-C and C-N bond forming reactions. Pyrolytic carbon provides an alternative to classic amorphous carbon-based materials that are either expensive or ill-suited to large-scale flow reactions.

Topics & Concepts

Pyrolytic carbonElectrochemistryRedoxCarbon fibersMaterials scienceAmorphous carbonNanotechnologyElectrodeChemical engineeringChemistryAmorphous solidPyrolysisOrganic chemistryMetallurgyComposite materialEngineeringPhysical chemistryComposite numberElectrochemical Analysis and ApplicationsElectrocatalysts for Energy ConversionCO2 Reduction Techniques and Catalysts