Atomically Precise Alkynyl- and Halide-Protected AuAg Nanoclusters Au<sub>78</sub>Ag<sub>66</sub>(C≡CPh)<sub>48</sub>Cl<sub>8</sub> and Au<sub>74</sub>Ag<sub>60</sub>(C≡CPh)<sub>40</sub>Br<sub>12</sub>: The Ligation Effects of Halides
Xiting Yuan, Sami Malola, Guocheng Deng, Fengjiao Chen, Hannu Häkkinen, Boon K. Teo, Lan‐Sun Zheng, Nanfeng Zheng
Abstract
= 4) and 84, respectively, consistent with their spherical shapes. Both clusters exhibit unusual multivalent redox properties.
Topics & Concepts
NanoclustersChemistryHalideCrystallographyElectron shellShell (structure)Magic number (chemistry)Ligand (biochemistry)MetalCluster (spacecraft)Coordination numberElectronic structureInorganic chemistryIonComputational chemistryMaterials scienceBiochemistryProgramming languageComputer scienceOrganic chemistryComposite materialReceptorIonizationNanocluster Synthesis and ApplicationsAdvanced Nanomaterials in CatalysisGold and Silver Nanoparticles Synthesis and Applications