One-step hydrothermal preparation of a novel 2D MXene-based composite electrode material synergistically modified by CuS and carbon dots for supercapacitors
Yuchun Li, Jiachen Liu, Tianle Gong, Changzhi Liang, Lin Li, Xuemei Lin, Zongrong Ying, Huangyan Liu
Abstract
2D material MXene is one of the most interesting electrode materials due to its vast range of potential applications in electrochemical energy storage and conversion in recent years. Herein we fabricated a novel 2D MXene-based composite electrode material by using hydrothermally synthetized CuS and carbon dots (CDs) to synergistically decorate Ti 3 C 2 T x . The introduction of CuS and CDs increases the interlayer spacing of Ti 3 C 2 T x , which reduces the stacking of Ti 3 C 2 Tx unfavorable to the electrochemical performance . The optimal C-Ti 3 C 2 T x /CuS composite electrode has an excellent specific capacitance of 1186 F·g −1 at a current density of 1 A·g −1 , which is much higher than that of Ti 3 C 2 T x samples decorated with single CuS or with single CDs, illustrating that CuS and CDs have the outstanding synergistic improvement effect to MXene on the electrochemical performance. When the current density rises to 10 A·g −1 , the sample still maintains a capacitance of 907 F·g −1 , corresponding to a capacitance retention rate of 76.5%. After 1000 cycles at a current density of 1 A·g −1 , the capacitance remains 67% of the initial value. These demonstrate that the C-Ti 3 C 2 T x /CuS composite electrode material has a great promising practical potential in fabricating high-performance supercapacitors . The new finding about the outstanding synergistic effect of CDs and transition metal compounds on improving MXene’s electrochemical performance suggests a possible effective way for preparing the high-performance MXene-based electrode materials.