Electrochemical cycloaddition of hydrazones with cyanamide for the synthesis of substituted 5-amine-1,2,4-triazoles
Minghua Yang, Rui Jiang, Yangxiu Mu, Yu Hong, Yaya Wan, Jing Hou, Dong Tang
Abstract
generation of hydrazones with cyanamide using KI as the catalyst and electrolyte. This strategy could be smoothly conducted with simple reaction conditions at room temperature without the addition of a chemical oxidant in an undivided cell, and cyanamide has been proven to be of great value in electrosynthesis.
Topics & Concepts
CyanamideElectrosynthesisAmine gas treatingElectrochemistryChemistryCycloadditionElectrolyteCatalysisCombinatorial chemistryOrganic chemistryElectrodePhysical chemistryClick Chemistry and ApplicationsSynthesis and Biological EvaluationRadical Photochemical Reactions