The synergistic effect of Fe3O4/g-C3N4 for persulfate activation in sulfate radical photo-Fenton
Muhamad Diki Permana, Takahiro Takei, Anjuman Ara Khatun, Norio Saito, Diana Rakhmawaty Eddy, Nobuhiro Kumada
Abstract
The Fe 3 O 4 /g-C 3 N 4 composite has been successfully synthesized using coprecipitation method. The light absorption capabilities of g-C 3 N 4 and Fe 3 O 4 demonstrate synergistic effect in activating persulfate (PS). This synergistic effect occurs at Fe 3 O 4 loading of 22–35 mass%, which has the effectiveness of hole-electron separation. The Fe−N coordination bonds were present, reflecting the interfacial chemical interactions between g-C 3 N 4 and Fe 3 O 4 . The PS-activated Fe 3 O 4 /g-C 3 N 4 system can completely degrade methyl orange (MO) in 15 min under visible light illumination (λ > 420 nm). Radical scavenging experiments show that SO 4 •− , • OH, • O 2 −, and h + play a role in the degradation of organic pollutants. Other organic pollutants, such as methylene blue, rhodamine B, crystal violet, and phenol were also successfully degraded, indicating that this system has strong non-selective oxidative capabilities. Therefore, the Fe 3 O 4 /g-C 3 N 4 /PS system has high photocatalytic activity, high magnetic properties and stability, and potential for application in the water treatment of organic pollutants.