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Synthesis of Ambient Cured GGBFS Based Alkali Activated Binder Using a Sole Alkaline Activator: A Feasibility Study

Thandiwe Sithole, Nelson Tsotetsi, Tebogo Mashifana

2021Applied Sciences13 citationsDOIOpen Access PDF

Abstract

Utilisation of industrial waste-based material to develop a novel binding material as an alternative to Ordinary Portland Cement (OPC) has attracted growing attention recently to reduce or eliminate the environmental footprint associated with OPC. This paper presents an experimental study on the synthesis and evaluation of alkali activated Ground granulated blast furnace slag (GGBFS) composite using a NaOH solution as an alkaline activator without addition of silicate solution. Different NaOH concentrations were used to produce varied GGBFS based alkali activated composites that were evaluated for Uncofined Compressive Strength (UCS), durability, leachability, and microstructural performance. Alkali activated GGBFS composite prepared with 15 M NaOH solution at 15% L/S ratio achieved a UCS of 61.43 MPa cured for 90 days at ambient temperatures. The microstructural results revealed the formation of zeolites, with dense and non-porous morphology. Alkali activated GGBFS based composites can be synthesized using a sole alkaline activator with potential to reduce CO2 emission. The metal leaching tests revealed that there are no potential environmental pollution threats posed by the synthesized alkali activated GGBFS composites for long-term use.

Topics & Concepts

Ground granulated blast-furnace slagMaterials scienceCompressive strengthGeopolymerAlkali metalLeaching (pedology)Composite materialPortland cementActivator (genetics)Composite numberChemical engineeringCementChemistryEnvironmental scienceOrganic chemistryGeneSoil scienceBiochemistryEngineeringSoil waterConcrete and Cement Materials ResearchMagnesium Oxide Properties and ApplicationsRecycling and utilization of industrial and municipal waste in materials production
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