Flexible Carbon Nanotube‐Epitaxially Grown Nanocrystals for Micro‐Thermoelectric Modules
Qun Jin, Yang Zhao, Xuehao Long, Song Jiang, Cheng Qian, Feng Ding, Ziqiang Wang, Xiaoqi Li, Zhi Yu, Juan He, Yujie Song, Hailong Yu, Ye Wan, Kaiping Tai, Ning Gao, Jun Tan, Chang Liu, Hui–Ming Cheng
Abstract
Abstract Flexible thermoelectric materials have attracted increasing interest because of their potential use in thermal energy harvesting and high‐spatial‐resolution thermal management. However, a high‐performance flexible micro‐thermoelectric device (TED) compatible with the microelectronics fabrication process has not yet been developed. Here a universal epitaxial growth strategy is reported guided by 1D van der Waals‐coupling, to fabricate freestanding and flexible hybrids comprised of single‐wall carbon nanotubes and ordered (Bi,Sb) 2 Te 3 nanocrystals. High power factors ranging from ≈1680 to ≈1020 µW m −1 K −2 in the temperature range of 300–480 K, combined with a low thermal conductivity yield a high average figure of merit of ≈0.81. The fabricated flexible micro‐TED module consisting of two p–n couples of freestanding thermoelectric hybrids has an unprecedented open circuit voltage of ≈22.7 mV and a power density of ≈0.36 W cm −2 under ≈30 K temperature difference, and a net cooling temperature of ≈22.4 K and a heat absorption density of ≈92.5 W cm −2 .