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Porous In<sub>2</sub>O<sub>3</sub> Microcubes Decorated with SnO<sub>2</sub> Nanoparticles for Enhanced Room Temperature Detection of SF<sub>6</sub> Gas Decomposition Products

Luqman Ali Khan, Jie Jiang, Liping Zhu

2025ACS Applied Nano Materials6 citationsDOI

Abstract

Due to its superior dielectric properties and ability to prevent electrical arcing, sulfur hexafluoride (SF 6 ) is widely employed in high-voltage electrical systems, including gas-insulated switchgear (GIS). Detecting SF 6 decomposition products is critical for monitoring and addressing issues related to partial discharge activities in GIS equipment. Despite the growing demand, developing cost-effective and energy-efficient sensors for SF 6 decomposition detection remains a challenge. In this study, we synthesized nanocomposites consisting of porous indium(III) oxide (In 2 O 3 ) microcubes decorated with Tin(IV) oxide (SnO 2 ) nanoparticles (SnO 2 –In 2 O 3 ) using a simple hydrothermal technique. Gas sensors based on SnO 2 –In 2 O 3 nanocomposites demonstrated excellent performance in detecting SF 6 decomposition products at room temperature. The SnO 2 decoration on the surface of the porous In 2 O 3 microcubes significantly enhanced the sensing response to 20 ppm of hydrogen sulfide (H 2 S), achieving a high response value of 33 at room temperature (25 °C), which is 6.9 times that of pure In 2 O 3 sensors. This innovative approach utilizing nanocomposite microcube-based materials offers significant promise for advancing the design of efficient gas sensors for SF 6 decomposition detection.

Topics & Concepts

NanoparticleMaterials scienceDecompositionPorosityChemical engineeringNanotechnologyChemistryComposite materialEngineeringOrganic chemistryGas Sensing Nanomaterials and SensorsZnO doping and propertiesTransition Metal Oxide Nanomaterials
Porous In<sub>2</sub>O<sub>3</sub> Microcubes Decorated with SnO<sub>2</sub> Nanoparticles for Enhanced Room Temperature Detection of SF<sub>6</sub> Gas Decomposition Products | Litcius