Competition and cooperativity of hydrogen-bonding and tetrel-bonding interactions involving triethylene diamine (DABCO), H<sub>2</sub>O and CO<sub>2</sub>in air
Jianming Yang, Qinwei Yu, Fangling Yang, Ka Lu, Chaoxian Yan, Wei Dou, Lizi Yang, Panpan Zhou
Abstract
Triethylene diamine (DABCO) can interact with H<sub>2</sub>O and CO<sub>2</sub>in air to form dimeric and trimeric complexes<italic>via</italic>hydrogen bond, tetrel bond as well as van der Waals interactions.
Topics & Concepts
ChemistryDABCOCooperativityHydrogen bondDiaminePolymer chemistryCompetition (biology)OctaneOrganic chemistryMoleculeEcologyBiochemistryBiologyCarbon dioxide utilization in catalysisCrystallography and molecular interactionsCO2 Reduction Techniques and Catalysts