TEMPO Radical-Functionalized Supramolecular Coordination Complexes with Controllable Spin–Spin Interactions
Wei‐Ling Jiang, Zhiyong Peng, Bin Huang, Xiao‐Li Zhao, Di Sun, Xueliang Shi, Hai‐Bo Yang
Abstract
via the crystal-to-amorphous transformation induced by mechanical grinding and solvent vapor stimuli was also successfully realized. The unique and controllable inter- and intramolecular spin-spin interactions in this work reveal new insights for the understanding and manipulation of spin-spin interactions and may open up a new way to develop organic spin materials in the future.
Topics & Concepts
Intramolecular forceChemistrySupramolecular chemistryIntermolecular forceElectron paramagnetic resonanceCrystallographyZero field splittingCounterionSpin (aerodynamics)Spin statesChemical physicsPulsed EPRSpin polarizationCrystal structureStereochemistrySpin echoMoleculeNuclear magnetic resonanceElectronIonPhysicsInorganic chemistryRadiologyThermodynamicsMedicineQuantum mechanicsOrganic chemistryMagnetic resonance imagingMagnetism in coordination complexesMetal-Organic Frameworks: Synthesis and ApplicationsSupramolecular Chemistry and Complexes